铅锌矿山开发导致的重金属在环境介质中的积累

以连续提取法和相关性分析研究了土法冶炼锌、铅锌和矿山开采导致的重金属在废渣及环境介质土壤、溪流沉积物中的积累，并分析了其环境危害性。结果显示，贵州赫章土法炼锌导致的重金属Pb、Zn、Cd在环境介质中的积累相当高。水城杉树林铅锌矿山开采引起的重金属积累则相对较低，但也明显高于背景值；土壤和沉积物中的铁矿物对重金属有强烈的固定作用。除残渣态外，Pb、Zn在土壤、炼锌废渣中主要呈铁锰氧化物结合态，沉积物中则为碳酸盐结合态。可交换态Pb、Zn含量变异较大，但在炼锌废渣、土壤中含量明显高于河流沉积物，暗示铅锌矿开发对土壤环境的潜在危害更大。     

埃达克岩及其成矿作用和相关问题的讨论

本文初步探讨了埃达克岩与相关大型矿床的关系，指出与埃达克岩浆有关的分异同化作用在一定条件下可以形成大型矿床；同时也强调了成矿后矿床保存的重要性。由于造山带的剥蚀速率快，导致和埃达克岩浆演化密切相关的形成于地壳浅部的大型斑岩矿床的保存有时限。因此在中国东部及“三北”地区中生代以前的造山带中，埃达克岩能否作为寻找相关大型矿床的标志值得商榷；但在新生代的西藏地区则是有可能的。近十年的研究认为中国东部侏罗纪—白垩纪的类似岩石并不属于埃达克岩系列，而是橄榄安粗岩及高钾钙碱性岩石系列。它们主要来源于富集地幔的部分熔融(不排除有下地壳物质混染的可能)及其后的结晶分异；一些中生代的斑岩型铜—金矿床和浅成低温热液矿床与此有关。     

Contrast in Fluid M etallogeny between the Tianmashan Au-S Deposit and the Datuanshan Cu Deposit in Tongling, Anhui Province

A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongling, Anhui Province. The major reasons for the formation of the stratabound skarn Au-S ore deposit in Tianmashan and the stratabound skarn Cu ore deposit in Datuanshan are analyzed in accordance with this contrast. The magmatic pluton in Tianmashan is rich in Au and poor in Cu, but that in Datuanshan is rich in Cu and Au. The wallrock strata in Tianmashan contain Au-bearing pyrite layers with some organic substance but those in Datuanshan contain no such layers. Moreover, the ore-forming fluids in Tianmashan are dominantly magmatic ones at the oxide and sulfide stages, but those with high content of Cu in Datuanshan are mainly groundwater fluids. In addition, differences in compositional evolution and physicochemical condition variation of the ore-forming fluids result in gradual dispersion     

~(40)Ar/~(39)Ar Dating of Deformation Events and Reconstruction of Exhumation of Ultrahigh-Pressure Metamorphic Rocks in Donghai, East China

Recent investigations reveal that the ultrahigh-pressure metamorphic (UHPM) rocks in the Donghai region of East China underwent ductile and transitional ductile-brittle structural events during their exhumation. The earlier ductile deformation took place under the condition of amphibolite facies and the later transitional ductile-brittle deformation under the condition of greenschist facies. The hanging walls moved southeastward during both of these two events. The 40Ar/39Ar dating of muscovites from muscovite-plagioclase schists in the Haizhou phosphorous mine, which are structurally overlain by UHPM rocks, yields a plateau age of 218.0±2.9 Ma and isochron age of 219.8Ma, indicating that the earlier event of the ampibolite-facies deformation probably took place about 220 Ma ago. The 40Ar/39Ar dating of oriented amphiboles parallel to the movement direction of the hanging wall on a decollement plane yields a plateau age of 213.1±0.3 Ma and isochron age of 213.4±4.1 Ma, probably representing the age o     

Re-Os Age of Cu-Ni Ores from the Huangshandong Cu-Ni Sulfide Deposit in the East Tianshan Mountains and Its Implication for Geodynamic Processes

An isochron age of 282±20 (95% conf. limit) Ma of the sulfide ores in the Huangshandong Cu-Ni sulfide deposit, the East Tianshan Mountains has been obtained through Re-Os isotopic measurement. The age implies that the Cu-Ni sulfide deposit and other related deposits in the same area occurred in a Permian extensional environment of post-collision instead of Devonian-Early Carboniferous ophiolite-related oceanic or island arc environments inferred before. It shares the same ages with the orogenic and epithermal gold deposit systems in the same area. An initial 187Os/188Os ratio of 0.25±0.04 (1σ) and a γos value of 99 on average display the participation of large quantities of crustal components into the rock-forming and ore-forming system during mineralization and magmatic emplacement.     

Late Caledonian Ductile Thrusting Deformation in the Central East Kunlun Belt, Qinghai, China and Its Significance: Evidence from Geochronology

A high-angle ductile thrusting deformation with top-to-the-north movement penetratively developed in the Proterozoic-Early Paleozoic metamorphic rocks along the Central East Kunlun belt. The deformed rocks suffered epidote-amphibolite facies metamorphism. On the basis of our previous study, we present more data in this paper to further support that the ducdle thrust deformation occurred in the later Caledonian and more detailed information about the deformation. A zircon U-Pb concordant age of 446±2.2 Ma of a deformed granodiorite in the ductile thrust zone was obtained and can be interpreted as the lower limit of the deformation. A syntectonically crystallized and also strongly deformed hornblende Ar/ Ar dating gives an Ar/Ar plateau age of 426.5±3.8 Ma, which represents the deformation age. A strongly orientated muscovite gives an Ar/Ar plateau age of 408±1.6Ma, representing the cooling age after the peak temperature, constraining the upper limit of the ductile thrust deformation. This ductile thru     

An X-Ray Diffraction Study of an Inclusion in Diamond from the Luobusha Chromite Deposit in Tibet, China

Diamond was found in podiform chromitites of ophiolite and harzburgite from Luobusha, Tibet. There are silicate inclusions in some diamond grains from this area. In the present work, the CCD (charge coupled detector) technology of X-ray powder diffraction was applied to the study of the inclusion in diamond from the ophiolite of Tibet. Diffraction patterns are obtained even though the inclusion is only 20 μm in crystal size. The results show that the inclusion in diamond consists of talc and clinochrysotile. Therefore, it is clear that the diamond from the ophiolite of Luobusha, Tibet, is natural diamond rather than a synthetic one.     

SHRIMP Age and Geochemistry of the Bikou Volcanic Terrane: Implications for Neoproterozoic Tectonics on the Northern Margin of the Yangtze Craton

The Bikou volcanic terrane is predominated by subalkaline tholeiitic lavas. Rock samples display lower initial ratios of Sr and Nd, 0.701248-0.704413 and 0.511080-0.512341 respectively. 207Pb and 208Pb are significantly enriched in the lavas. Most samples have positive εNd, which indicates that the magma was derived from EM-type mantle source, while a few samples with negative εNd indicate that there was contamination in the magma evolution. Magma differentiation is demonstrated by variations of LREE and LILE from depletion to enrichment. Additionally, normalized REE patterns and trace elements showed that lavas from the Bikou volcanic terrane have similar characteristics to those of basalts in arc settings caused by subduction and collision. Analyses showed that the Bikou volcanic terrane is a volcanic arc. New evidence proved that the Hengdan Group, north of the Bikou arc, is a turbidite terrane filling a forearc basin. Consequently, the Bikou volcanic terrane and the Hengdan turbidite terrane const     

An Experimental Calibration on the Sphalerite-Galena Sulfur Isotope Geothermometer

A new experimental calibration was undertaken in this study to get a more reliable sphalerite-galena sulfur isotope geothermometer. The experimental conditions selected in study were very similar to those of natural hydrothermal solution. The high-precision SF6 method was used in sulfur isotope analyses. The obtained calibration curve for sulfur isotope fractionation between sphalerite and galena can be expressed with the equation 10001nαSp-Gn= 0.74×106T-2+0.08.     

贵州峨眉山玄武岩喷发期的岩相古地理研究

贵州峨眉山玄武岩喷发，从动态的角度可以分为茅口期晚期和龙潭期（吴家坪期），龙潭期又可分为三个喷发旋回，对应于四个不同的岩相古地理环境，体现了东吴运动在造成贵州地区地壳抬升、下沉和接受最大海侵之后，又上升、拉张、沉陷带发生地裂（又称峨眉地裂）以及地幔物质喷溢等地质活动，具间歇性和多旋回性的特点。本文从研究海陆变迁入手，揭示峨眉山玄武岩喷发与沉积作用的内在联系，进而探讨其与金、锑等矿产的成因联系，提出该期各相区与成矿区的形成模式。通过对贵州峨眉山玄武岩不同喷发期岩相古地理的研究可以看到，茅口期晚期和龙潭期早期海域的沉积韵律和相带展布格局与玄武岩喷发的间歇性和多旋回性特征完全一致。玄武岩的喷发为成矿提供了物质基础，玄武岩喷发的间歇期又为沉积矿产的富集提供机遇。这种岩浆期后气液以富硅和二氧化碳为特征的玄武岩，本身富含铁、锰、铜、铅、锌、锑、砷、汞、金、银、氟、磷以及一些稀散和放射性元素等成矿组分。在喷发过程中，气液成分有一定变化，各阶段和离岩浆的远近距离不同以及喷发性质和环境差异，形成了火山气液矿床、火山沉积矿床和沉积矿床的不同成矿带。